用比电导法研究活性炭的吸附特性     

陈以良 《广东海洋大学学报》1992,(1)

用比电导法研究两种活性炭自稀水溶液中吸附强电解质硫酸铬和硫酸铜的吸附平衡特性。结果表明,在本文的研究条件下,两种活性炭对硫酸铬和硫酸铜都有吸附作用。同时,活性炭吸附硫酸铜的吸附平衡特性可以用 Freundlich 方程式来描述。研究的结果对固体在溶液中的吸附基础理论以及处理工业废水具有一定的意义。  相似文献   

Dissolution and depletion of ferromagnesian minerals from Holocene tephra layers in an acid bog,New Zealand,and implications for tephra correlation     

A. P. W. Hodder  P. J. De Lange  D. J. Lowe 《第四纪科学杂志》1991,6(3):195-208

This study examines the depletion of ferromagnesian silicate minerals from a sequence of thin, distal, mainly rhyolitic tephra layers of Holocene age preserved in an acid peat bog (Kopouatai), North Island, New Zealand. The rate of such depletion has been fast, as indicated by the complete loss of biotite from one tephra layer (Kaharoa Tephra), in which it is normally dominant, in only ca. 770 yr. Chemical dissolution is advocated as the likely cause for the depletion, with amphiboles and other mineral grains commonly showing etch pits, microcaves, and other characteristic surface solution features. Theoretical thermodynamic and kinetic models show a marked increase in the rate of dissolution of all ferromagnesian minerals under conditions of low pH (< 4), but that where silica concentrations in solution are high the relative proportions of minerals remaining are unaffected. However, where concentrations of dissolved silica are low, as in most bog environments, the relative proportions of ferromagnesian minerals are affected as well as absolute amounts being decreased. Amphiboles are depleted relative to pyroxenes, consistent with kinetic studies. The results show that the identification and correlation of tephras on the basis of relative abundances of ferromagnesian minerals alone may be unreliable, and emphasise the need to use multiple criteria in such studies.  相似文献   

Modeling on adsorption–desorption of trace metals to suspended particle matter in the Changjiang Estuary     

Y. Y. Zhang  E. R. Zhang  J. Zhang 《Environmental Geology》2008,53(8):1751-1766

The uptake and release of trace metals (Cu, Ni, Zn, Cd, and Co) in estuaries are studied using river and sea end-member waters and suspended particulate matter (SPM) collected from the Changjiang Estuary, China. The kinetics of adsorption and desorption were studied in terms of environmental factors (pH, SPM loading, and salinity) and metal concentrations. The uptake of the metals studied onto SPM occurred mostly within 10 h and reached an asymptotic value within 40 h in the Changjiang Estuary. As low pH river water flows into the high pH seawater and the water become more alkaline as it approaches to the seaside of estuary, metals adsorb more on SPM in higher pH water, thus, particulate phase transport of metal become increasingly important in the seaward side of the estuary. The percentage of adsorption recovery and the distribution coefficients for trace metals remained to be relatively invariable and a significant reduction only occurred in very high concentrations of metals (>0.1 mg L⁻¹). The general effect of salinity on metal behavior was to decrease the degree of adsorption of Cu, Zn, Cd, Co, and Ni onto SPM but to increase their adsorption equilibrium pH. The adsorption–desorption kinetics of trace metals were further investigated using Kurbatov adsorption model. The model appears to be most useful for the metals showing the conservative behavior during mixing of river and seawater in the estuary. Our work demonstrates that dissolved concentration of trace metals in estuary can be modeled based on the metal concentration in SPM, pH and salinity using a Kurbatov adsorption model assuming the natural SPM as a simple surfaced molecule.  相似文献   

Phosphorus transport in shallow groundwater in peri-urban Kampala, Uganda: results from field and laboratory measurements   总被引：1，自引：0，他引：1  

N. R. Kulabako  M. Nalubega  R. Thunvik 《Environmental Geology》2008,53(7):1535-1551

To understand Phosphorus (P) sources and transport processes in the subsurface in Bwaise III Parish, Kampala, P attenuation and adsorption capacities of soils were studied in situ and from laboratory measurements. Relationships between sorption parameters and soil matrix properties, rates and mechanism of the adsorption process and soil P fractions were also investigated. P was generally higher in the wet than the dry season, but for both seasons, the maximum was 5 mgP/l. P transport mechanisms appeared to be a combination of adsorption, precipitation, leaching from the soil media and by colloids with the latter two playing an important role in the wet season. The sorption process comprised two phases with the first stage rate constants being about fourfold those of the second stage. The Langmuir isotherm described the sorption data well (R ² ≥ 0.95) with the second soil layer exhibiting the highest sorption maximum (C _max) (average value 0.6 ± 0.17 mgP/gDW). The best prediction of C _max had organic carbon, Ca, available P and soil pH. Residual P consisting mostly of organics was the main fraction in all the layers followed by inorganic HCl-P and NaOH-P in the top and middle layers, respectively. Loosely bound P (NH₄Cl-P) was the least fraction (<0.4% of total P) in all layers indicating the high binding capacity of P by the soils. The study results suggest that P dynamics is related to Ca, Fe and organic carbon content of the soils.  相似文献   

THERIA_G: a software program to numerically model prograde garnet growth   总被引：6，自引：4，他引：2  

F. Gaidies  C. de Capitani  R. Abart 《Contributions to Mineralogy and Petrology》2008,155(5):657-671

We present the software program THERIA_G, which allows for numerical simulation of garnet growth in a given volume of rock along any pressure–temperature–time (P–T–t) path. THERIA_G assumes thermodynamic equilibrium between the garnet rim and the rock matrix during growth and accounts for component fractionation associated with garnet formation as well as for intracrystalline diffusion within garnet. In addition, THERIA_G keeps track of changes in the equilibrium phase relations, which occur during garnet growth along the specified P–T–t trajectory. This is accomplished by the combination of two major modules: a Gibbs free energy minimization routine is used to calculate equilibrium phase relations including the volume and composition of successive garnet growth increments as P and T and the effective bulk rock composition change. With the second module intragranular multi-component diffusion is modelled for spherical garnet geometry. THERIA_G allows to simulate the formation of an entire garnet population, the nucleation and growth history of which is specified via the garnet crystal size frequency distribution. Garnet growth simulations with THERIA_G produce compositional profiles for the garnet porphyroblasts of each size class of a population and full information on equilibrium phase assemblages for any point along the specified P–T–t trajectory. The results of garnet growth simulation can be used to infer the P–T–t path of metamorphism from the chemical zoning of garnet porphyroblasts. With a hypothetical example of garnet growth in a pelitic rock we demonstrate that it is essential for the interpretation of the chemical zoning of garnet to account for the combined effects of the thermodynamic conditions of garnet growth, the nucleation history and intracrystalline diffusion. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.

F. GaidiesEmail:

  相似文献   

Controls on porphyroblast size along a regional metamorphic field gradient     

David M. Hirsch 《Contributions to Mineralogy and Petrology》2008,155(4):401-415

Garnet-bearing schists from the Waterville Formation of south-central Maine provide an opportunity to examine the factors governing porphyroblast size over a range of metamorphic grade. Three-dimensional sizes and locations for all garnet porphyroblasts were determined for three samples along the metamorphic field gradient spanning lowest garnet through sillimanite grade, using high-resolution X-ray computed tomography. Comparison of crystal size distributions to previous data sets obtained by stereological methods for the same samples reveals significant differences in mode, mean, and shape of the distributions. Quantitative textural analysis shows that the garnets in each rock crystallized in a diffusion-controlled nucleation and growth regime. In contrast to the typical observation of a correlation between porphyroblast size and position along a metamorphic field gradient, porphyroblast size of the lowest-grade specimen is intermediate between the high- and middle-grade specimens’ sizes. Mean porphyroblast size does not correlate with peak temperatures from garnet-biotite Fe-Mg exchange thermometry, nor is post-crystallization annealing (Ostwald Ripening) required to produce the observed textures, as was previously proposed for these rocks. Robust pseudosection calculations fail to reproduce the observed garnet core compositions for two specimens, suggesting that these calc-pelites experienced metasomatism. For each of these two specimens, Monte Carlo calculations suggest potential pre-metasomatism bulk compositions that replicate garnet core compositions. Pseudosection analyses allow the estimation of the critical temperatures for garnet growth: ∼481, ∼477, and ∼485°C for the lowest-garnet-zone, middle-garnet-zone, and sillimanite-zone specimens, respectively. Porphyroblast size appears to be determined in this case by a combination of the heating rate during garnet crystallization, the critical temperature for the garnet-forming reaction and the kinetics of nucleation. Numerical simulations of thermally accelerated, diffusion-controlled nucleation, and growth for the three samples closely match measured crystal size distributions. These observations and simulations suggest that previous hypotheses linking the garnet size primarily to the temperature at the onset of porphyroblast nucleation can only partially explain the observed textures. Also important in determining porphyroblast size are the heating rate and the distribution of favorable nucleation sites.  相似文献   

水溶液中聚合物在粘土上的吸附          下载免费PDF全文

王修林 《海洋与湖沼》1993,24(4):420-427

水溶液中聚合物在粘土上的吸附对于聚合物污染防治和污水处理等都有重要意义。Scheutjens-Fleer理论是应用范围最广的聚合物吸附理论,适应于从单体到长链高聚物,从链无相互作用的稀溶液到纯聚合物的吸附研究。本文简要介绍了有关聚合物吸附的重要参数,包括吸附量、耦合分数或直接表面覆盖、平均层厚度和链段密度,以及相应的测定方法。文中分析了影响聚合物吸附研究发展的主要问题,指出水溶液中聚合物在粘土上的吸附研究的发展方向是综合研究吸附等温线和A/V效应、耦合分数、吸附层厚度、吸附分级现象和对粘土层间的影响,并与Scheutjens-Fleer理论计算结果进行比较。  相似文献   

耗氧速率(OUR)测量方法的实验研究   总被引：4，自引：0，他引：4  

李冰  孙英兰  李玉瑛 《中国海洋大学学报(自然科学版)》2006,36(3):456-460

目前多采用分批实验法和呼吸测量仪测量耗氧速率,而耗氧速率的测量对于研究活性污泥数学模型中的动力学参数及废水特性鉴定具有重要意义。本文根据OUR测量方法的基本原理设计了1种简易的OUR测量装置,为检验测量装置的有效性,设计了相关实验进行验证。在内源呼吸实验中,测定了所用活性污泥的内源呼吸速率是5.1mgO2/L·h,污泥的衰减系数是0.0137h-1,比文献值略高。基质降解实验对人工配水(葡萄糖和淀粉)的耗氧速率进行了测定,实验结果显示有3个显著不同的耗氧速率,分别为35mg/L·h,13mg/L·h,6mg/L·h,它们各代表葡萄糖降解、淀粉降解和内源呼吸的速率。内源呼吸速率高于前1个实验是由于基质降解过程中污泥量增加所致。并计算出异养菌产率系数Kd为0.63mgVSS/mgCOD,Kd略低于文献值。实验结果证明,该装置能很好的实现测量目的。  相似文献   

粘土矿物去除赤潮生物的动力学研究   总被引：12，自引：3，他引：12  

俞志明  邹景忠  马锡年  王利峡 《海洋与湖沼》1995,26(1):1-6

于１９９２年４－９月进行粘土矿的絮凝赤潮生物（微型原甲藻）的动力学研究；考察粘土种类、浓度、第二组分（ＰＡＣＳ）和ＰＨ等因素对絮凝速率的影响，建立粘土矿物絮凝赤潮生物的动力学模型，从理论上分析和讨论各种因素的影响，并提出提高絮凝速率的方法和途径。结果表明，高岭土体系絮凝速率大于蒙脱土体系，其速率方程可用双分子反应来描述。其中，速率常数随絮凝过程发生变化；粒子间的相互作用能和作用半径是控制和影响絮凝  相似文献   

低硼氢氧化镁的制备及热分解动力学参数     

高荣杰  冯丽娟  杜敏  宁滨  梁丽 《中国海洋大学学报(自然科学版)》2002,32(5):789-794

本文以水合氯化镁、工业氨水为原料制备出了低硼含量的纯度 >99%的氢氧化镁和氧化镁。利用差热 -热重 (DTA- TG)、X-射线衍射 (XRD)、透射电子显微镜 (TEM)等手段 ,对氢氧化镁的热稳定性、相结构、表观状态以及脱水动力学参数进行了分析。结果为 :氢氧化镁以束状纤维和片状粉末共存 ,在 6 2 3K基本完成脱水反应生成氧化镁 ,其脱水反应的表观活化能 E为135 .4 k J· mol-1,指前因子 A为 5 .15× 10 10 ,反应级数 n为 1.10  相似文献